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投稿时间:2018-10-25
投稿时间:2018-10-25
中文摘要: 锂电池用电解铜箔的力学性能会在铜箔生成后的一段时间内发生剧烈变化,并直至趋于稳定,将铜箔进行常温老化处理的过程中发现 :铜箔的抗拉强度衰减 42%,延伸率较初始增加 1.2~1.4 倍左右,而且主要发生在老化前 36h 内 ;可能的原因为铜箔电沉积过程中的有机添加剂在老化过程中发生分解扩散,铜箔晶粒变大,发生重结晶。经过老化处理后,铜箔力学性能稳定,客户端在锂电池设计和铜箔使用时,可以精准地预测铜箔集流体在锂电池内部使用过程中的抗拉强度和延伸率,有效避免因铜箔材料的性能变化导致的各种安全问题。
Abstract:The mechanical property of electrolytic copper foil used in lithium battery will change rapidly after the formation of copper foil until it becomes stable. The aging process in room temperature showed that:the tensile strength of copper foil attenuation of 42%, and the elongation increased about 1.2-1.4 times, but the changes take place within 36 hours before aging. This may have occurred because the organic additive that participated in the process of electro-deposition is decomposed on the process of aging, the size of grain get bigger, and the grains recrystallized. After the aging treatment, the mechanical property of copper foil is stable, when the customers design the lithium battery and use the copper foil, they can precisely forecast the tensile strength and the elongation of the copper foil which is used inside the lithium battery, to avoid various safety issues that are happened by the changes of the performance of the copper foil.
文章编号:202001014 中图分类号:TG113.2
基金项目:
引用文本:
何铁帅.重结晶对锂电池用电解铜箔力学性能的影响[J].铜业工程,2020,(1):52-54


