铜业工程:2023(1):19-27
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Cu-Cr-Zr-Nb合金组织及耐磨性研究
李龙健, 康慧君, 张家郡, 曹兴豪, 刘志锋, 王同敏
(大连理工大学材料科学与工程学院,辽宁省凝固控制与数字化制备技术重点实验室)
Microstructure and Wear Resistance of Cu-Cr-Zr-Nb Alloy
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投稿时间:2023-01-10    修订日期:2023-01-29
中文摘要: 借助Nb元素在Cu-Cr-Zr合金中的作用,通过真空感应熔炼结合两步轧制-时效工艺制备Cu-Cr-Zr-Nb合金,并对其组织及耐磨性进行了研究。结果表明:经过两步轧制-时效工艺的合金中存在着大量的位错、纳米析出相和纳米变形孪晶,使合金的强度显著提升。通过Nb元素合金化,在合金中引入了均匀分布的Cr2Nb微米颗粒,同时在合金中存在微米和纳米尺度Cr颗粒,利用微米和纳米颗粒的协同强化使合金的性能提升。针对其耐磨性,铸态合金的摩擦系数在0.6以上,体积磨损量随实验载荷的增加而增加。经过轧制-时效工艺,由于合金强度和硬度的提升,其摩擦系数下降至0.6以下,体积磨损量稳定在0.2 mm3以下,磨损机制主要以粘着磨损和疲劳磨损为主。
Abstract:Cu-Cr-Zr-Nb alloy was designed by considering the role of Nb element in Cu-Cr-Zr alloy. The alloy samples were prepared by vacuum induction melting and a two-step rolling-aging process,and their microstructure and wear resistance were studied. The results showed that a large number of dislocations,nano-precipitates,and deformation twins existed in the samples after the two-step rolling-aging process,which improved the strength of the alloy. By alloying Nb element,uniformly distributed Cr2Nb particles were introduced into the alloy, and micro- and nano-sized Cr particles were observed in the alloy. The properties of the alloy were effectively enhanced by the synergistic effect of micro- and nano-sized particles. The friction coefficient of the as-cast samples was generally above 0.6,and the volume wear increased with the increase of the experimental load. After the rolling-aging process,the friction coefficient of the aging samples decreased to less than 0.6 due to the increase in strength and hardness,and the volume wear was below 0.2 mm3 steadily. The adhesive wear and fatigue wear were the main wear mechanism.
文章编号:20230110001     中图分类号:TG146
基金项目:国家自然科学基金项目(52271025,51971052,51927801,51690163);辽宁省“兴辽英才”计划项目(XLYC2007183);大连市科技创新基金项目(2020JJ25CY002,2020JJ26GX045)
引用文本: 李龙健,康慧君,张家郡,曹兴豪,刘志锋,王同敏.Cu-Cr-Zr-Nb合金组织及耐磨性研究[J].铜业工程,2023,(1):19-27