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投稿时间:2023-04-10 修订日期:2023-05-17
投稿时间:2023-04-10 修订日期:2023-05-17
中文摘要: 为研究苯并三氮唑(BTA)在锂电铜箔抗氧化方面的应用,运用高温烘箱、扫描电子显微镜(SEM)、电化学工作站等手段对BTA进行了研究。研究表明,铜箔在实验浓度范围内(BTA质量浓度0.1~2.0 mg/L),经BTA、 BTA+植酸(PA)、 BTA+硅烷偶联剂(KH792)三种钝化液处理后,放置150 ℃高温烘箱保温10 min,均发生了不同程度的氧化变色,表面轻微泛黄。经BTA+草酸(OA)配置成的钝化液处理后,同样放置150 ℃高温烘箱保温10 min,铜箔变色不明显,并且其微观形貌均未见明显变化, BTA和OA配合使用形成的钝化膜膜电阻和反应电阻相对更高。
Abstract:The application of benzotriazole (BTA) in the oxidation resistance of lithium copper foil was studied by means of high temperature oven, scanning electron microscope (SEM) and electrochemical workstation. The results show that the copper foil treated with BTA, BTA+ phytic acid (PA) and BTA+ silane coupling agent (KH792) in the experimental concentration range (BTA mass concentration is 0.1 to 2.0 mg/l) has different degrees of oxidation discoloration and slight yellows after being placed in the oven at 150 ℃ for 10 min. The copper foil treated with BTA+ oxalic acid (OA) passivation solution showed no obvious discoloration under the same conditions, and no significant micromorphology changes were observed by electron microscope. The film resistance and reaction resistance of the passivation film formed by BTA and OA were relatively higher.
keywords: lithium copper foil benzotriazole chromium-free passivation high temperature oxidation micromorphology
文章编号:20230410001 中图分类号:TQ153.14
基金项目:
引用文本:
宋言,朱若林.苯并三氮唑在锂电铜箔抗氧化方面的研究[J].铜业工程,2023,(3):103-107


