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投稿时间:2023-05-27 修订日期:2023-06-15
投稿时间:2023-05-27 修订日期:2023-06-15
中文摘要: 采用真空感应熔炼结合两步低温轧制-时效处理(CRA)工艺制备了Cu-Cr-Co-Ti合金,分析了峰时效样品的室温性能和高温性能。通过电子背散射衍射(EBSD)和透射电子显微镜(TEM)观察了Cu-Cr-Co-Ti样品的微观组织。结果表明:两步低温轧制-时效处理能够在铜基体中引入高密度的变形孪晶片层、位错和纳米析出相,有效提升了Cu-Cr-Co-Ti合金的室温强度和导电率。具有面心立方结构的纳米Cr析出相均匀弥散地分布在铜基体内,和基体具有立方-立方位向关系。Co和Ti元素能够聚集在纳米Cr析出相表面上,阻碍了析出相在时效处理和高温变形过程的粗化和长大现象。在经过300 ℃高温拉伸测试后,纳米Cr析出相仍稳定地阻碍了晶界运动,显著提升了Cu-Cr系合金的高温性能。经过500 ℃时效处理2 h后,峰时效CRA样品的室温抗拉强度为571 MPa、导电率为73.9%IACS (国际退火铜标准)。高密度孪晶片层具有优异的热稳定性,将铜合金在300 ℃和400 ℃下的高温强度分别提升至481 MPa和379 MPa。
中文关键词: Cu-Cr-Co-Ti合金 低温轧制-时效 高温性能
Abstract:Cu-Cr-Co-Ti alloys were prepared by vacuum induction melting and two-step cryorolling-aging (CRA) process. The room-temperature and elevated-temperature properties of the peak-aged samples were investigated, respectively. The microstructures of Cu-CrCo-Ti samples were analyzed using electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). The results showed that CRA treatment could introduce the high-density deformation twin bundles, dislocations, and nanoscale precipitates, thus improving the room-temperature strength and electrical conductivity. The nanoscale precipitates with a face-centered cubic (fcc) structure distribute uniformly in matrix and obtain the orientation relationship of cube-on-cube with matrix. Co and Ti elements tended to aggregate at the periphery of nanoscale Cr precipitates to restrain it coarsening and growth during the aging treatment and elevated-temperature deformation. After the elevated-temperature tensile tests at 300 ℃, the nanoscale Cr precipitate could impede the motion of grain boundary, leading to the optimization of elevated-temperature properties. The room-temperature strength (571 MPa) and electrical conductivity (73.9%IACS, IACS: International Annealed Copper Standard) of peak-aged CRA sample were obtained after aging at 500 ℃ for 2 h. The high-density twin bundles with excellent thermal stability could elevate the elevated-temperature tensile strengths at 300 ℃ and 400 ℃ to 481 MPa and 379 MPa, respectively.
文章编号:20230527002 中图分类号:TG146
基金项目:国家自然科学基金项目(52271025,51971052,51927801,51690163,52001161);辽宁省“兴辽英才”计划项目(XLYC2007183);江苏省自然科学基金项目(BK20200695)
引用文本:
张家郡,康慧君,李龙健,李仁庚,刘志锋,王同敏.Cu-Cr-Co-Ti合金微观组织和高温性能研究[J].铜业工程,2023,(3):23-31


