铜业工程:2023(5):17-24
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形变时效工艺对Cu-Sc合金组织及性能的影响
高帆, 张兴德, 高浩, 杨甜, 曹飞, 姜伊辉
(西安理工大学材料科学与工程学院,导电材料与复合技术教育部工程研究中心,陕西省电工材料与熔渗技术重点实验室)
Microstructure and Properties of Cu-Sc Alloy Deformation Aging Process
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投稿时间:2023-08-23    修订日期:2023-09-18
中文摘要: 研究了形变时效工艺对不同Sc含量的Cu-xSc合金(x=0.1,0.2,0.3,0.4 ;质量分数)微观组织、力学性能和导电性能的影响。结果显示,随着Sc含量增加, Cu-xSc合金基体晶粒尺寸逐渐减小; Cu-Sc合金硬度随着Sc含量的增加而增加,导电率随着Sc含量的增加而下降。不同Sc含量的 Cu-xSc合金均在 400 ℃时效 60 min后达到峰值时效,从而获得合理的硬度和导电率匹配。为了进一步提升合金的强度和导电率,对Cu-xSc合金进行两步形变时效处理,观察组织发现两步形变时效后基体中产生大量变形孪晶,变形孪晶与纳米析出相相互作用显著提升Cu-xSc合金的力学性能与导电性能。预时效先析出的纳米相会诱导产生大量孪晶束和高密度位错,有利于在终时效过程中促进固溶原子析出,从而提升合金的强度和导电率。两步形变时效后经计算综合评估, Cu-0.4Sc合金具有更优的强度和导电率匹配,其抗拉强度和导电率分别为656 MPa和67.8%IACS ,较一步形变时效分别提升了19.7%和18.7%。
Abstract:In this paper, the effects of deformation aging process on the microstructure, mechanical and electrical properties of Cu-xSc (x = 0.1, 0.2, 0.3, 0.4; mass fraction) alloys with different Sc contents were studied. The results showed that with the increase of Sc content, the grain size of Cu-xSc alloys matrix decreased gradually. The hardness of Cu-xSc alloy increased with the increase of Sc content, and the conductivity decreased with the increase of Sc content. Cu-xSc alloys with different Sc contents all reached the peak aging after aging at 400 ℃ for 60 min, so as to obtain a reasonable matching of hardness and conductivity. In order to further improve the strength and conductivity of the alloy, Cu-xSc alloys were subjected to two-step deformation aging treatment. It was found that a large number of deformation twins were generated in the matrix after two-step deformation aging, and the interaction between deformation twins and nano-precipitates significantly improved the mechanical and electrical properties of Cu-xSc alloys. The nano-phase precipitated before pre-aging would induce a large number of twin beams and high-density dislocations, which was beneficial to promote the precipitation of solid solution atoms during the final aging process, thereby improving the strength and conductivity of the alloy. After two-step deformation and aging, Cu-0.4Sc alloy had better matching of strength and conductivity. The tensile strength and conductivity of Cu-0.4Sc alloy were 656 MPa and 67.8%IACS, respectively, which were 20.6% and 18.7% higher than those of one-step deformation and aging.
文章编号:20230823001     中图分类号:TF813;TF804.2
基金项目:国家自然科学基金项目(51974244,52271137)
引用文本: 高帆,张兴德,高浩,杨甜,曹飞,姜伊辉.形变时效工艺对Cu-Sc合金组织及性能的影响[J].铜业工程,2023,(5):17-24