铜业工程:2023(5):10-16
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球形Cu粉粒径对谐波结构TiB2/Cu复合材料组织及性能的影响
曹飞, 许英琴, 张兴德, 韩非, 姜伊辉
(西安理工大学材料科学与工程学院,导电材料与复合技术教育部工程研究中心,陕西省电工材料与熔渗技术重点实验室)
Microstructure and Properties of Heterogeneous TiB2/Cu Composites Based on Different Spherical Cu Particle Sizes with a Harmonic Structure
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投稿时间:2023-08-31    修订日期:2023-10-03
中文摘要: 以Cu-Ti-B体系为研究对象,利用球磨和振动混粉方法进行构型设计,通过热压烧结制备出TiB2富集区(硬区)包裹纯Cu区(软区)的谐波结构TiB2/Cu复合材料。研究了球形Cu粉粒径对谐波结构复合材料微观组织、传导性能和力学性能的影响。结果显示:当球形Cu粉粒径较小时,谐波结构特征不明显,且强塑性较差。当球形Cu粉粒径大于15 μm时,谐波结构特征逐渐显著。当Cu粉粒径在53~75 μm时,谐波结构复合材料的致密度和传导性能最优,同时TiB2富集区与纯Cu区之间的不兼容变形有助于在纯Cu区产生背应力使其强化,并在TiB2富集区产生相应的正应力使其韧化,背应力与正应力的共同作用使谐波结构 TiB2/Cu复合材料发挥较好的协调变形能力,获得更优的强塑性匹配。随着球形Cu粉粒径进一步增加,复合材料的强塑性逐渐降低。因此,在谐波结构复合材料中,调控合适的非均匀组织特征对复合材料综合性能至关重要。
Abstract:Based on the configuration design through ball milling and vibration mixing method, the heterogeneous TiB2/Cu composites a harmonic structure containing the TiB2 rich zone (hard zone) and the pure Cu zone (soft zone) were prepared by hot pressing sintering. The effect of spherical Cu particle size on the microstructure, conductivity and mechanical properties of heterogeneous composite was studied. The results showed that when the spherical Cu particle size was small, the harmonic structure was not obvious, and the strength and plasticity was poor. When the spherical Cu particle size was larger than 15 μm, the harmonic structure was gradually obvious. When the spherical Cu particle size was in the range of 53~75 μm, the relative density and conductivity of the composite was the highest, and the incompatibility deformation between TiB2 rich zone and pure Cu zone helped to generate back stress in pure Cu zone to strengthen it, and the corresponding normal stress in TiB2 rich zone to toughen it. The combined effect of back stress and normal stress made the hard zone and soft zone of the harmonic TiB2/Cu composite exert better coordination deformation ability, which resulted in a better combination of strength and plasticity. With the further increase of spherical Cu particle size, the strength and plasticity of the composite decreased gradually. Therefore, it was very important to regulate an appropriate heterogeneous structure in the composite.
文章编号:20230831005     中图分类号:TG146
基金项目:国家自然科学基金项目(U21A2051,51904241)
引用文本: 曹飞,许英琴,张兴德,韩非,姜伊辉.球形Cu粉粒径对谐波结构TiB2/Cu复合材料组织及性能的影响[J].铜业工程,2023,(5):10-16