铜业工程:2024(1):22-28
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La2O3掺杂Ti3SiC2/Cu复合材料的制备与性能
伊洪勇1, 陈忠文2, 王俊青1, 张云龙1, 李成海1, 张瑞霞1, 潘佳琦1, 李文博1, 贾辰凡1
(1.佳木斯大学材料科学与工程学院;2.中建材佳星玻璃(黑龙江)有限公司)
Preparation and Properties of La2O3-Doped Ti3SiC2/Cu Composites
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投稿时间:2024-02-01    修订日期:2024-02-29
中文摘要: 铜合金作为热管理材料长期服役时,会出现冷-热循环条件下的结构性失效问题,因此考虑将具有低膨胀系数的MAX相材料引入到铜合金中,来降低复合材料的热膨胀性。Ti3SiC2是一种兼具陶瓷和金属的优良特性的三元层状陶瓷材料,具有自润滑、高韧性、高导电性等特点。作为增强相,Ti3SiC2能够提高Cu基复合材料的摩擦性能,降低复合材料的热膨胀系数,因此被应广泛用于电子封装材料、热管理材料等领域。本文将稀土氧化物La2O3引入到Ti3SiC2/Cu复合材料中,研究了La2O3掺杂含量对Ti3SiC2/Cu复合材料物相组成、表面形貌、显微硬度和摩擦因数等的影响。研究发现,利用热压烧结技术能够获得致密度较高的 Ti3SiC2/Cu复合材料,相对密度在 98.5%以上。适量掺杂 La2O3后,Ti3SiC2/Cu复合材料的显微硬度有所增加,能够实现Ti3SiC2/Cu复合材料的弥散强化。随着La2O3掺杂量增加,Ti3SiC2/Cu复合材料的摩擦因数呈现出先降低后增加的趋势。在 Cu基复合材料中添加 Ti3SiC2,能够起到润滑的作用,有利于降低摩擦因数。本研究可为 Ti3SiC2/Cu复合材料的工程应用提供试验依据。
中文关键词: Ti3SiC2  Cu复合材料  耐磨性  显微硬度
Abstract:Co structural failure of copper alloy under the condition of cold-heat cycle occurred when it was applied as thermal management material for a long time. Therefore, it was considered to introduce MAX phase material with low expansion coefficient into the copper alloy to reduce the thermal expansion of the composites. Ti3SiC2 was a three-layer ceramic material with excellent properties of both ceramic and metal, which had the characteristics of self-lubrication, high toughness and high electrical conductivity. As a reinforcing phase, Ti3SiC2 can improve the friction properties of Cu-based composites, then it reduced the thermal expansion coefficient of the composite material, so Ti3SiC2/Cu composites should be widely used in electronic packaging materials, thermal management materials and other fields. In this paper, rare earth oxide La2O3 was introduced into Ti3SiC2/Cu composite to survey the effects of La2O3 doping content on the phase composition, surface morphology, microhardness and friction factor of Ti3SiC2/Cu composites. It was found that the high density Ti3SiC2/Cu composites can be obtained by hot pressing sintering technology, then the relative density was more than 98.5%. After proper La2O3 doping, the microhardness of Ti3SiC2/Cu composites was increased, which can realize the dispersion strengthening of Ti3SiC2/Cu composites. With the increase of La2O3 doping, the friction coefficient of Ti3SiC2/Cu composites decreased first and then increased. Adding Ti3SiC2 to Cu matrix composites can play a lubricating role and was conducive to reducing friction factor. This research can provide experimental basis for the engineering application of Ti3SiC2/Cu composites.
文章编号:20240201002     中图分类号:TG174.4
基金项目:黑龙江省教育厅基础科研业务费项目(2019-KYYWF-1373)
引用文本: 伊洪勇,陈忠文,王俊青,张云龙,李成海,张瑞霞,潘佳琦,李文博,贾辰凡.La2O3掺杂Ti3SiC2/Cu复合材料的制备与性能[J].铜业工程,2024,(1):22-28