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铜业工程:2024(5):97-106
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高强导电耐磨Cu-Fe-C复合材料的设计与制备
肖天成1, 邹存磊1,2, 张爽1, 李长鸣1, 曲晚勤1, 王峻赫1, 董闯1
(1. 大连交通大学材料科学与工程学院;2. 大连交通大学连续挤压教育部工程研究中心)
Design and Preparation of High Strength Electrical Conductive and Wear Resisting Cu-Fe-C Composites
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投稿时间:2024-03-25    修订日期:2024-05-22
中文摘要: 以高强导电耐磨Cu-Fe-C复合材料为研究对象,采用真空熔铸及变形热处理工艺,制备了不同C含量的Cu-Fe-C复合材料。通过X射线衍射(XRD)、金相显微镜(OM)、扫描电子显微镜(SEM)、电导率测定仪、维氏硬度测试仪、电子万能试验机等设备对Cu-Fe-C复合材料的组织结构和性能进行了检测与分析。结果表明,固溶温度对Cu-Fe-C复合材料的力学和电学性能有显著影响,材料硬度随固溶温度升高而降低,在1000 ℃时硬度达到最低值HV 77,且观察到了明显的过烧现象。复合材料的电导率也随固溶温度升高而降低,但在固溶温度900 ℃后就趋于不变,电导率达到最低值18%IACS,这主要是由于Fe和C元素已充分固溶。经过热轧、固溶、冷轧时效后,相较于铸态和固溶态,材料的电导率和硬度均有明显的升高,分别达到了 56%IACS 和 HV 155。此外,随着 C 含量的增加,复合材料的界面会成为脆弱的铜石墨界面,强度和电导率稍有降低。复合材料的摩擦系数随C含量的增加明显降低,说明石墨的析出明显提高了复合材料的耐磨性。
中文关键词: Cu-Fe-C  热处理  摩擦磨损  硬度  电导率
Abstract:In this paper, Cu-Fe-C composites with different carbon contents were prepared by vacuum melting casting and deformation heat treatment. The microstructures and properties of Cu-Fe-C composites were tested and analyzed by X-ray diffraction, metallographic microscope, scanning electron microscope, conductivity tester, Vickers hardness tester and electronic universal testing machine. The results show that the mechanical and electrical properties of Cu-Fe-C composites are significantly affected by the solution temperature. The hardness of the composites decreases with increasing solution temperature. The hardness reaches the lowest value of HV77 at 1000 ℃, and overburning is observed. The conductivity of the composite also decreases with the increase of the solution temperature, but it tends to remain unchanged after the solution temperature of 900 ℃, and the conductivity reaches the lowest value of 18%IACS, mainly because Fe and C elements have been sufficiently solid dissolved. After hot rolling, solid solution and cold rolling, the conductivity and hardness of the material were significantly increased, reaching 56%IACS and HV155, compared with the as-cast and solid solution. In addition, with the increase of C content, the strength and conductivity of the composite are slightly reduced due to the weak copper-graphite interface. The friction coefficient of the composite decreases with the increase of C content, indicating that the precipitation of graphite significantly improves the wear resistance of the composite.
文章编号:20240325001     中图分类号:TG146
基金项目:国家自然科学基金项目(52171134,51901033);大连市科技创新基金应用基础研究项目(2022JJ12GX039);大连市优秀青年科技人才项目(2022RY14);辽宁省“兴辽英才计划”项目(XLYC2203113)
引用文本: 肖天成,邹存磊,张爽,李长鸣,曲晚勤,王峻赫,董闯.高强导电耐磨Cu-Fe-C复合材料的设计与制备[J].铜业工程,2024,(5):97-106