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投稿时间:2024-08-08 修订日期:2024-11-13
投稿时间:2024-08-08 修订日期:2024-11-13
中文摘要: 以新能源汽车用铜合金线材作为研究对象,针对Cu-Sn合金体系在电热丝、汽车线束等应用中的焊接性能不足及电阻调节范围小等问题,通过下引连铸工艺制备直径为12.5 mm的Cu-1Sn和Cu-1Sn-0.5P合金铸杆,并利用单台倒立式盘拉机将铸杆经多道次冷拉拔为Φ2.6 mm线材。采用金相显微镜(OM)、扫描电子显微镜(SEM)、拉伸试验机、电阻率仪对Cu-1Sn和Cu-1Sn-0.5P合金的微观组织演变、力学性能及导电性能进行综合对比分析。结果表明,与Cu-1Sn合金相比, Cu-1Sn-0.5P合金线材具有以下特点:P元素的添加在Cu-1Sn-0.5P合金中形成了富P相,并在冷拉拔过程中变形为纤维增强组织;由于铜基体中固溶的P原子及富P的第二相对位错存在阻碍作用, Cu-1Sn-0.5P合金线材抗拉强度由577.5 MPa提升至796.1 MPa,但塑性略有下降,延伸率由1.0%降低至0.67%,断面收缩率由65.8%下降为36.0%;由于P元素的添加增加了电子的散射,使得Cu-1Sn-0.5P合金线材的导电率由52.3%IACS降至24.6%IACS。经过冷拉拔之后, Cu-1Sn-0.5P合金线材的导电率又出现2.45%IACS的回升。
Abstract:Cu-1Sn and Cu-1Sn-0.5P alloy casting rods with a diameter of 12.5 mm were prepared by downward continuous casting process, in view of the insufficient weldability and small resistance adjustment range of Cu-Sn alloy system used in new energy vehicles. The cast rods were drawn into 2.6 mm wires by multi-pass cold drawing with a single inverted disc drawing machine. The microstructure evolution, mechanical properties and electrical conductivity of Cu-1Sn and Cu-1Sn-0.5P alloys were comprehensively compared and analyzed by metallographic microscope, scanning electron microscope, tensile test and resistivity meter. Compared with Cu-1Sn alloy, the addition of P element formed a P-rich phase in Cu-1Sn-0.5P alloy and deformed into fiber-reinforced structure during cold drawing. The tensile strength of Cu-1Sn-0.5P alloy wire increased from 577.5 MPa to 796.1 MPa due to the hindering effect of solid solution P atoms and P-rich second phase dislocations in the copper matrix. However, the plasticity decreased slightly while the elongation decreased from 1.0% to 0.67%, and the reduction of area decreased from 65.8% to 36.0%. Finally, the conductivity of Cu-1Sn-0.5P alloy wire decreased from 52.3%IACS to 24.6%IACS due to the increase of electron scattering caused by the addition of P element. However, after cold drawing, the conductivity increased by 2.45%IACS.
keywords: Cu-Sn-P alloy downward continuous casting cold drawing mechanical property electrical conductivity
文章编号:20240808001 中图分类号:TF813;TF804.2
基金项目:赣鄱俊才支持计划·主要学科学术和技术带头人培养项目(20232BCJ22028);中央引导地方科技发展资金项目(2022ZDD03081)
引用文本:
徐苗苗,洪志远,郭祊鹤,姚 瑶,甘 强,吴龙军,陈 岩.P元素对下引连铸Cu-Sn-P合金组织性能的影响[J].铜业工程,2025,(4):26-34


