铜业工程:2025(4):26-34
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P元素对下引连铸Cu-Sn-P合金组织性能的影响
徐苗苗1,2, 洪志远1,2, 郭祊鹤1,2, 姚 瑶1,2, 甘 强1,2, 吴龙军1,2, 陈 岩1,2
(1. 江西铜业集团有限公司 稀贵稀散金属材料江西省重点实验室,江西 南昌 330096;2. 江西铜业技术研究院有限公司,江西 南昌 330500)
Addition of P Element on Microstructure and Properties of Downward Continuous Casting Cu-Sn-P Alloy
XU Miaomiao1,2, HONG Zhiyuan1,2, GUO Fanghe1,2, YAO Yao1,2, GAN Qiang1,2, WU Longjun1,2, CHEN Yan1,2
(1. Jiangxi Copper Corporation Limited, Jiangxi Provincial Key Laboratory of Rare and Scattered Metals Materials,Nanchang 330096, China;2. Jiangxi Copper Technology Research Institute Co., Ltd., Nanchang 330500, China)
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投稿时间:2024-08-08    修订日期:2024-11-13
中文摘要: 以新能源汽车用铜合金线材作为研究对象,针对Cu-Sn合金体系在电热丝、汽车线束等应用中的焊接性能不足及电阻调节范围小等问题,通过下引连铸工艺制备直径为12.5 mm的Cu-1Sn和Cu-1Sn-0.5P合金铸杆,并利用单台倒立式盘拉机将铸杆经多道次冷拉拔为Φ2.6 mm线材。采用金相显微镜(OM)、扫描电子显微镜(SEM)、拉伸试验机、电阻率仪对Cu-1Sn和Cu-1Sn-0.5P合金的微观组织演变、力学性能及导电性能进行综合对比分析。结果表明,与Cu-1Sn合金相比, Cu-1Sn-0.5P合金线材具有以下特点:P元素的添加在Cu-1Sn-0.5P合金中形成了富P相,并在冷拉拔过程中变形为纤维增强组织;由于铜基体中固溶的P原子及富P的第二相对位错存在阻碍作用, Cu-1Sn-0.5P合金线材抗拉强度由577.5 MPa提升至796.1 MPa,但塑性略有下降,延伸率由1.0%降低至0.67%,断面收缩率由65.8%下降为36.0%;由于P元素的添加增加了电子的散射,使得Cu-1Sn-0.5P合金线材的导电率由52.3%IACS降至24.6%IACS。经过冷拉拔之后, Cu-1Sn-0.5P合金线材的导电率又出现2.45%IACS的回升。
Abstract:Cu-1Sn and Cu-1Sn-0.5P alloy casting rods with a diameter of 12.5 mm were prepared by downward continuous casting process, in view of the insufficient weldability and small resistance adjustment range of Cu-Sn alloy system used in new energy vehicles. The cast rods were drawn into 2.6 mm wires by multi-pass cold drawing with a single inverted disc drawing machine. The microstructure evolution, mechanical properties and electrical conductivity of Cu-1Sn and Cu-1Sn-0.5P alloys were comprehensively compared and analyzed by metallographic microscope, scanning electron microscope, tensile test and resistivity meter. Compared with Cu-1Sn alloy, the addition of P element formed a P-rich phase in Cu-1Sn-0.5P alloy and deformed into fiber-reinforced structure during cold drawing. The tensile strength of Cu-1Sn-0.5P alloy wire increased from 577.5 MPa to 796.1 MPa due to the hindering effect of solid solution P atoms and P-rich second phase dislocations in the copper matrix. However, the plasticity decreased slightly while the elongation decreased from 1.0% to 0.67%, and the reduction of area decreased from 65.8% to 36.0%. Finally, the conductivity of Cu-1Sn-0.5P alloy wire decreased from 52.3%IACS to 24.6%IACS due to the increase of electron scattering caused by the addition of P element. However, after cold drawing, the conductivity increased by 2.45%IACS.
文章编号:20240808001     中图分类号:TF813;TF804.2
基金项目:赣鄱俊才支持计划·主要学科学术和技术带头人培养项目(20232BCJ22028);中央引导地方科技发展资金项目(2022ZDD03081)
引用文本: 徐苗苗,洪志远,郭祊鹤,姚 瑶,甘 强,吴龙军,陈 岩.P元素对下引连铸Cu-Sn-P合金组织性能的影响[J].铜业工程,2025,(4):26-34