铜业工程:2026(2):10-19
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Zr添加对Cu-15Ni-8Sn合金微观结构和力学性能的影响
乐顺聪1, 余琪1, 张晋涵2, 张鹏飞1, 席安武1, 钟方友1, 胡延波1, 刘启阳1
(1.江西铜业加工事业部,江西 南昌 330096;2.江西江铜高精铜板带有限公司,江西 南昌 330096)
Effect of Zr Addition on Microstructure and Mechanical Properties of Cu-15Ni-8Sn Alloy
LE Shuncong1, YU Qi1, ZHANG Jinhan2, ZHANG Pengfei1, XI Anwu1, ZHONG Fangyou1, HU Yanbo1, LIU Qiyang1
(1.JCC Processing Business Division,Nanchang 330096,China; 2.JCC Copper Strip Company Limited,Nanchang 330096,China)
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投稿时间:2025-08-07    修订日期:2025-12-19
中文摘要: 铍青铜因成本高、工艺复杂且易产生有毒粉尘,其生产与应用受到限制,而Cu-15Ni-8Sn合金因综合性能优异,成为理想的替代材料。本文系统研究了添加0.8%(质量分数)的Zr对Cu-15Ni-8Sn合金组织演化与力学性能的影响机制。结果表明,铸态合金呈现枝晶组织,主要由α-Cu基体、γ-CuNi2Sn相,以及骨骼状、颗粒状Ni4SnZr相组成。固溶处理后,枝晶消失,Ni4SnZr相因热力学稳定性得以保留,而CuNi2Sn相完全溶解。时效结果表明,合金的硬度随着时效时间的延长先增加后降低,硬度降低主要源于不连续沉淀组织的形成。此外,时效温度的提高促进了不连续沉淀的析出,导致合金峰值硬度下降。冷轧变形可显著调控组织演化:当变形量为78%时,通过抑制不连续沉淀并促进有序相析出,使合金经400 ℃时效1 h后峰值硬度提升至383HV; 当变形量为90%时,因诱发了再结晶软化,硬度回落至378.5HV。
Abstract:Beryllium bronze faces limitations in production and application due to high manufacturing costs, complex processing, and toxic dust. In contrast, Cu-15Ni-8Sn alloy has emerged as an ideal alternative material owing to excellent comprehensive properties. This study systematically investigated the influence of 0.8% (mass fraction) Zr addition on the microstructural evolution and mechanical properties of Cu-15Ni-8Sn alloy. Results demonstrated that the as-cast alloy exhibited a dendritic structure, primarily composed of α-Cu matrix, γ-CuNi2Sn phase, and skeletal/particulate Ni4SnZr phases. After solution treatment, the dendritic structure was eliminated, with the Ni4SnZr phase retained due to thermodynamic stability, while CuNi2Sn phase completely dissolved. Aging behavior studies revealed that the alloy's hardness initially increased and then decreased with aging time. The decline was primarily attributed to the formation of discontinuous precipitation. Moreover, higher aging temperatures accelerated discontinuous precipitation, leading to reduced peak hardness. Cold rolling significantly modulated microstructural evolution: a 78% cold deformation rate suppressed discontinuous precipitation while promoting the precipitation of ordered phases, achieving a peak hardness of 383HV after aging at 400 ℃ for 1 h. However, 90% deformation induced recrystallization softening, causing hardness to decrease to 378.5HV.
文章编号:20250807001     中图分类号:TG146.11
基金项目:江西铜业股份有限公司电磁线用低银合金铜杆制备技术研究与开发项目(SYYJ2024002)
引用文本: 乐顺聪,余琪,张晋涵,张鹏飞,席安武,钟方友,胡延波,刘启阳.Zr添加对Cu-15Ni-8Sn合金微观结构和力学性能的影响[J].铜业工程,2026,(2):10-19