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投稿时间:2025-08-25 修订日期:2026-01-04
投稿时间:2025-08-25 修订日期:2026-01-04
中文摘要: 针对江西铜业股份有限公司武山铜矿外排水硬度高(350~900 mg/L,CaCO3)、季节性水源短缺及管道结垢风险问题,通过实验室小试筛选出国产争光树脂(工作交换容量550~600 mmol/L),优化运行参数(流速12 m/h,再生液浓度6%~8% NaCl),并在120 m3/h工业规模验证其可行性。结果表明:软化水硬度稳定控制在0~130 mg/L (以CaCO3计),Ryznar稳定指数(RSI)6.0~7.3,再生盐耗210~245 g/mol。成本与现有取水方式相当,吨水处理成本为0.755元,其中:盐0.684元,树脂0.069元,电0.002元。再生废液中重金属浓度符合《GB 25467—2010》排放标准(Pb<0.37 mg/L,Zn<0.45 mg/L)。该技术可实现废水回用率100%,解决了南阳河季节性断流影响生产的问题,为高硬度矿山废水处理提供了解决方案。
Abstract:In response to the high hardness of discharged water (350~900 mg/L CaCO3), seasonal water scarcity, and pipeline scaling risk at Wushan Copper Mine in Jiangxi, this study developed a softening and reuse process based on ion exchange resin. Laboratory-scale tests were conducted to select a domestic Zhengguang (working exchange capacity 550~600 mmol/L). Operating parameters were optimized (flow rate 12 m/h, regenerant concentration 6%~8% NaCl), and the feasibility was verified at an industrial scale of 120 m3/h. Results showed that the softened water hardness was stably controlled at 0~130 mg/L CaCO3, with a Ryznar stability index of 6.0~7.3. Regenerant salt consumption was 210~245 g/mol, and treatment cost per ton of water was 0.686 RMB/ton, of which the salt cost was 0.684 RMB/ton. Resin cost per cubic meter of softened water was 0.069 RMB/m3, and the average electricity cost for recycled water was 0.002 RMB/m3, comparable to current water intake cost. Concentrations of heavy metals in the regeneration waste complied with the GB 25467—2010 discharge standards (Pb<0.37 mg/L, Zn<0.45 mg/L). This technology addressed the production risk caused by seasonal water interruptions of the Nanyang River, achieved 100% wastewater reuse, and provided a solution for treating high-hardness mine wastewater.
keywords: ion exchange wastewater reuse hardness control regeneration salt consumption water quality stability index mining wastewater
文章编号:20250825001 中图分类号:TU991.26+2;TD218
基金项目:江西铜业股份有限公司武山铜矿外排水软化工业应用关键技术研究项目(WTYJ2022004)
引用文本:
张绪贵,张健,黎希明,许新浩.离子交换技术在矿山外排水软化处理中的应用研究[J].铜业工程,2026,(3):113-124


