铜业工程:2026(2):1-9
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再生H65黄铜中铁元素对其组织和性能的影响
尤治博1, 钱高祥2, 赖士浩2, 张宇博1, 王同敏1, 李廷举1
(1.大连理工大学 材料科学与工程学院,辽宁 大连 116024; 2.江西云泰铜业有限公司,江西 鹰潭 335000)
Influence of Iron on Microstructure and Properties of Recycled H65 Brass
YOU Zhibo1, QIAN Gaoxiang2, LAI Shihao2, ZHANG Yubo1, WANG Tongmin1, LI Tingju1
(1.School of Materials Science and Engineering,Dalian University of Technology,Dalian 116024,China; 2.Yuntai Copper Co.,Ltd.,Yingtan 335000,China)
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投稿时间:2025-09-03    修订日期:2026-01-14
中文摘要: 铜合金再生利用是铜合金生产的重要环节。在H65黄铜再生过程中,Fe是常见的杂质元素,显著影响黄铜性能,需要严格控制其含量。本研究通过调控回收料配比,控制再生H65黄铜中Fe的质量分数,系统研究了铁元素对再生H65黄铜组织和性能的影响。研究表明,随着黄铜中Fe质量分数的增加,晶粒明显细化,极限拉伸强度、屈服强度和硬度增加,但延伸率和电导率下降。具体表现为,当Fe的质量分数从0.014%上升至0.051%,平均晶粒尺寸由64.2 μm下降至48.9 μm,屈服强度由105.9 MPa提高至122.1 MPa,硬度由74.5HV升至88.1HV,延伸率和电导率由62.6%和27.5%IACS分别降低至54.5%和25.8%IACS。电化学测试表明,H65黄铜的耐蚀性能随Fe质量分数的增加呈现先上升后下降的趋势。Fe的质量分数在0.04%以下时以固溶强化为主,继续升高则可能出现偏聚甚至析出。本研究为再生黄铜的成分设计、组织调控、性能优化提供了实验依据。
中文关键词: 再生黄铜  铁元素  力学性能  耐蚀性
Abstract:Recycling and reuse of copper alloys constitutes a crucial component in China""s copper alloy production. During the recycling of brass, iron (Fe) is a prevalent impurity element that can significantly impact brass properties, thus necessitating stringent limitation of iron in brass. This study achieved precise control of Fe content during brass recycling by regulating the input of recycled materials, and systematically investigated the influence of iron on microstructure and properties of recycled H65 brass. Results demonstrated that with increasing Fe content in brass, grains were significantly refined, and the ultimate tensile strength, yield strength and plasticity increased. However, this led to a decrease in elongation and electrical conductivity. Specifically, as Fe content increased from 0.014% to 0.051%, the average grain size decreased from 64.2 μm to 48.9 μm, yield strength increased from 105.9 MPa to 122.1 MPa, and hardness increased from 74.5 HV to 88.1 HV. Conversely, elongation decreased from 62.6% to 54.5%, and electrical conductivity decreased from 27.5%IACS to 25.8%IACS. On the other hand, electrochemical tests revealed that the average corrosion rate exhibited an initial decrease followed by an increase, indicating corrosion resistance initially improved but subsequently deteriorated with increasing Fe content. When Fe content was below 0.04%, solid solution strengthening predominated. Further increases may lead to elemental segregation or even precipitation. This research offered systematical guidance for optimizing economic benefits, controlling microstructural evolution, increasing corrosion resistance, and improving processing performance of recycled brass.
文章编号:20250903001     中图分类号:TG146.1+1
基金项目:国家自然科学基金项目(52171135); 重点新材料研发及应用国家科技重大专项(2025ZD0611000,子课题:2025ZD0611003)
引用文本: 尤治博,钱高祥,赖士浩,张宇博,王同敏,李廷举.再生H65黄铜中铁元素对其组织和性能的影响[J].铜业工程,2026,(2):1-9