Abstract:A large number of arsenic-containing waste residues are produced in the metallurgical and chemical processes,especially in Yunnan and Guangxi. A large number of arsenic-containing waste residues have not been properly disposed of, bringing enormous pressure to enterprises and environmental protection. Arsenic-containing waste residues are generally classified as HW24 or HW48 hazardous waste, which can pollute the atmosphere and groundwater and cause harm to human body if stored for a long time.At present, some arsenic-containing waste residues are incinerated or solidified landfill, which is not well utilized for resources. The methods of extracting valuable products from black copper mud, zinc secondary oxide, copper sulphate filter residue and arsenic-alkali residue are elaborated in detail, which can provide reference for industrialization and research of arsenic residue.