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投稿时间:2023-07-25 修订日期:2023-08-07
投稿时间:2023-07-25 修订日期:2023-08-07
中文摘要: 二氧化钌(RuO2)具备较高的电阻稳定性和较低的电阻温度系数,被广泛应用于制备厚膜电阻浆料的导电相。以无水氯化钌为原料,水为反应介质,选用绿色且经济的还原剂,利用水热还原法,得到了兼具单分散和高球形度的RuO2颗粒,可满足电阻浆料制备的需要。采用扫描电子显微镜(SEM)分析了 RuO2粉的形貌、粒径和团聚状态,以 X 射线衍射仪(XRD)检测颗粒的晶相,并利用电化学工作站测试了RuO2球形颗粒与RuO2/CuO复合材料的电阻特性。结果表明:单分散、球形度高、尺寸均匀的金红石型纳米RuO2的阻抗值最小,其导电性明显优于出现明显团聚的RuO2颗粒, RuO2/CuO也表现出较强的导电性。由阻抗测试结果可知, RuO2颗粒的加入可显著提升CuO的导电性。
中文关键词: 水热还原法 单分散球形氧化钌 电阻性能测试 纳米颗粒 RuO2/CuO复合材料
Abstract:Ruthenium dioxide (RuO2) exhibits high electrical resistance stability and a low temperature coefficient of resistance, making it widely used as the conductive phase in the preparation of thick-film resistor pastes. By employing anhydrous ruthenium chloride as the raw material and water as the reaction medium, monodisperse RuO2 powder with high sphericity through a liquid phase chemical reducing hydrothermal precipitation method were obtained. The morphology, particle size, and agglomeration of RuO2 powder were analyzed by using scanning electron microscopy (SEM), while the crystal phase of the powder was detected using an X-ray diffractometer (XRD). Additionally, the resistive properties of both RuO2 and RuO2/CuO were tested using an electrochemical workstation. The results showed that the monodispersed, high-sphericity, and uniformly sized nano RuO2 exhibited the lowest impedance, and its conductivity was significantly superior to RuO2 particles with obvious agglomeration. Moreover, compared to CuO, RuO2/CuO also displayed superior conductivity.
keywords: hydrothermal reduction method spherical ruthenium oxide electrochemical performance monodisperse nanoparticles RuO2/CuO composite material
文章编号:20230725002 中图分类号:TM54
基金项目:2022年秦创原引用高层次创新创业人才项目(QCYRCXM-2022-155)
引用文本:
韩光达,怡裕浩,薛 航,贾博谦,朱雪澎,邢 天.单分散RuO2球形颗粒的制备及RuO2/CuO电阻性能的研究[J].铜业工程,2023,(5):64-69


