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铜业工程:2024(6):18-24
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某高原区典型铬污染场地人体健康风险评价
王雷1,2,3,4,5, 李红霞1,2,3,4,5, 崔兴兰1,2,3,4,5, 史新悦1,2,3,4,5, 郑鹏1,2,3,4,5, 孙英春1,2,3,4,5, 杨晓莉6
(1. 中国有研科技集团有限公司 高品质有色金属绿色特种冶金国家工程研究中心;2. 有研资源环境技术研究院(北京)有限公司;3. 北京有色金属研究总院;4. 战略性有色金属绿色制造技术北京市工程研究中心;5. 有研工程技术研究院有限公司;6.6. 青海绿道环保生物科技有限公司)
A Formal Assessment of Human Health Risks Associated with Chromium Contamination in a Typical Site within a Plateau Region
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投稿时间:2024-02-21    修订日期:2024-03-19
中文摘要: 以某高原地区典型的铬污染场地为研究对象,采用经验判断和系统布点法相结合的方式进行布点采样。场地共设置了104个土壤采样点位,覆盖了表层、中层以及深层土壤样品。对这些样品进行了总Cr,Cr(Ⅵ),Fe(II),Fe(III),SO42-和Ca 6项分析。结果显示,该场地中钙、铁、铬等元素含量较高,为前期化学修复产生的影响,表明场地受到人为活动的影响显著,特别关注的污染物是Cr(Ⅵ),平均含量可达12.88 mg/kg,且离散程度较高,具有明显的污染迁移风险。结合《土壤环境建设用地土壤污染风险管控标准(试行)》(GB 36600—2018),进一步开展场地的危害识别、暴露和毒性评估,并进行风险表征,对吸入土壤颗粒物途径致癌效应、经口摄入土壤途径非致癌效应和吸入土壤颗粒物途径非致癌效应的土壤风险控制值进行了计算分析。分析结果表明,在该地区将Cr(Ⅵ)含量降至5.72 mg/kg时,可显著降低危害人体健康的风险。
Abstract:This study focused on a typical chromium-contaminated site in a high-altitude plateau region, employing a combination of empirical judgment and systematic site selection principles for sampling. A total of 104 soil sampling points were established, covering surface, intermediate, and deep soil layers. Analysis was conducted on these samples for six elements: total-Cr, Cr(Ⅵ), Fe(II), Fe(III), SO42-, and Ca. The results indicated elevated levels of calcium, iron, and chromium at the site, likely influenced by prior chemical remediation efforts, suggesting significant anthropogenic impact. The particular concern was the presence of Cr(Ⅵ), with an average concentration reaching 12.88 mg/kg and exhibiting high dispersion, posing a notable risk of pollutant migration. Combining the "Soil Environmental Quality Risk Control Standard for Soil Contamination of Development Land" (GB36600—2018), further assessment was conducted regarding hazard identification, exposure, toxicity evaluation, and risk characterization. Soil risk control values were calculated and analyzed for carcinogenic effects via inhalation of soil particles, non-carcinogenic effects via oral ingestion of soil, and non-carcinogenic effects via inhalation of soil particles. The analysis indicated that significantly reducing Cr(Ⅵ) levels to 5.72 mg/kg in the area could effectively mitigate health risks to human populations.
文章编号:20240221005     中图分类号:TF813; TF804.2
基金项目:国国家重点研发计划项目(2019YFC1805903)
引用文本: 王雷,李红霞,崔兴兰,史新悦,郑鹏,孙英春,杨晓莉.某高原区典型铬污染场地人体健康风险评价[J].铜业工程,2024,(6):18-24