铜业工程:2025(5):42-51
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微量Ag元素对Cu-Ag合金抗软化性能的影响及机理分析
王宛玉1, 王虎1,2, 郭慧稳2, 刘月梅2
(1. 中铝科学技术研究院有限公司,北京 102209;2. 中铝洛阳铜加工有限公司,河南 洛阳 471039)
Mechanism Analysis of Trace Ag Content Change on Softening Resistance of Cu-Ag Alloy
WANG Wanyu1,WANG Hu1, 2,GUO Huiwen2,LIU Yuemei2
(1. Chinalco Science and Technology Research Institute Co.,Ltd.,Beijing 102209,China;2. Chinalco Luoyang Copper Processing Co.,Ltd.,Luoyang 471039,China)
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投稿时间:2025-03-13    修订日期:2025-07-03
中文摘要: 电子元器件向大功率、小型化、高可靠性方向不断发展,对应用于这些元器件的铜带性能提出了更高要求。铜带不仅要维持高导电和良好导热性,还应具备更高的强度和抗软化能力。本项目采用场发射扫描电子显微镜的电子背散射(EBSD)、场发射透射电子显微镜(TEM)等表征手段,系统研究了微量Ag(0.0013%~0.0208%,质量分数)对Cu-Ag合金组织及抗软化性能的影响。结果表明,微量Ag可细化Cu-Ag合金微观组织,显著改善其在高温下的力学性能及抗软化性能,其中Ag质量分数为0.0208%的合金(S4)软化温度达到408 ℃,相较于低Ag合金(S1,0.0013%),软化温度提升了80 ℃,硬度提高了约26%。微量Ag固溶于基体中,会引发晶格畸变,对位错的滑移运动产生显著阻碍,从而有效延缓了合金的再结晶进程。此外,微量Ag的添加还能对晶界产生钉扎效应,显著抑制晶粒长大,延缓再结晶发生。分析表明,再结晶是导致合金发生高温软化现象的主要原因。
中文关键词: 铜合金  Ag微合金化  抗软化  再结晶  Ag偏析
Abstract:With the ongoing advancement of electronic components towards higher power, miniaturization, and enhanced reliability, the performance requirements for copper strips used in these components are also becoming increasingly stringent. Copper strips must not only maintain high electrical and thermal conductivity but also exhibit superior strength and resistance to softening. In this paper, characterization methods such as EBSD and TEM were employed to systematically investigate the influence of trace Ag (0.0013%~0.0208%) on the microstructure and anti-softening performance of Cu-Ag alloys. The research findings indicated that trace Ag can refine the microstructure of Cu-Ag alloys, significantly enhancing their mechanical properties at high temperatures and increasing softening temperature. Specifically, the softening temperature of alloy with 0.0208% Ag (S4) reached 408 ℃, which was 80 ℃ higher than that of alloy with lower Ag content (S1, 0.0013%), and the hardness increased by approximately 26%. Trace Ag was solid-solved in the matrix, causing lattice distortion and significantly impeding the slip movement of dislocations, thereby effectively retarding the recrystallization process of the alloy. Additionally, the addition of trace Ag also exerted a pinning effect on the grain boundaries, significantly inhibiting grain growth and delaying the occurrence of recrystallization. The analysis revealed that recrystallization was the primary cause of the high-temperature softening phenomenon of the alloy.
文章编号:20250313002     中图分类号:TG146.1+1 ;TG166.2
基金项目:国家重点研发计划项目(2023YFB3812601);中铝重点研发计划项目(ZT2417)
引用文本: 王宛玉,王虎,郭慧稳,刘月梅.微量Ag元素对Cu-Ag合金抗软化性能的影响及机理分析[J].铜业工程,2025,(5):42-51